
Plasma Pyrolysis
(Revised 9Feb99 at 20:15)
By Thomas A. Damberger, C.E.M.
ABSTRACT -
The problem of waste disposal continues to plague the health care
industry in the United States. Canyons have been transformed into
mountains of waste. Across the country, disposal sites are
closing without available replacement sites. Disposal costs
continue to rise. Incinerators cannot operate because they
release toxic air contaminants (TAC's) from the combustion
process into the environment.
Plasma pyrolysis, an electrotechnology at work, is an
environmentally benign answer to the waste disposal dilemma. A
new application of a proven technology, the plasna torch reaches
instantaneous arc temperatures of 21,000 degrees Fahrenheit. It
converts all organics into clean fuel gases and vitrifies
inorganics into an inert glassy rock. All by-products are
recyclable. There are a variety of uses for the vitreous glassy rock. It
can be used as concrete filler in roadbed construction, in
composition roofing and even for insulation. The product gas can
be used as a boiler gas or for methanol production.
Environmental pollution is eliminated as well as the long term
liability associated with disposal of medical waste at municipal
solid waste sites. Landfills will no longer be considered
"dumps" but sources of transportation fuel. Plasma
pyrolysis of both medical and municipal solid waste is an
innovative, environmentally sound solution to a complex and
growing problem.
INTRODUCTION -
Kaiser Permanente is one of the largest prepaid Health
Maintenance Organizations in the country. Kaiser spans twelve
regions throughout sixteen states and the District of Columbia.
The Southern California Region is one of the largest with about
200 buildings including eleven hospitals. We manage over ten
million square feet of floor space. Forty utilities provide
service to our facilities at an annual cost of over $42 million.
Transportation services throughout the region are provided by a
fleet of 425 vehicles.
Kaiser Permanente's rapid growth in Southern California places an
increased demand for additional energy services. There is a
direct correlation between energy consumption and environmental
pollution. Increased efficient use of energy improves
environmental quality. Our heightened environmental awareness
coupled with expanding membership growth produces a real dilemma.
We must meet the health care needs of our members while making
the best possible use of our energy and preserving environmental
resources. This includes reducing energy costs while meeting
environmental challenges. Ozone formation, brown clouds, acid
rain, burgeoning landfills, global warming and the greenhouse
effect come to mind when we talk of environmental deterioration.
THE PROBLEM -
With syringes washing ashore in New York, Florida and
California and "red bag" waste showing up at landfills,
the problem is further exacerbated by court ordered closures of
landfills. According to the Environmental Protection Agency
(EPA), half of the estimated 6,600 land-fills in the country are
being closed over the next five years. Additionally, even though
a hospital or health care facility may not violate any of the
Resource Conservation and Recovery Act (RCRA) regulations, it is
still held liable under common law for improper handling or
disposing of its pathological and biological waste should any
harm be done to any person or property. This cradle-to-grave
mentality carries a lifetime liability for all generators of
medical waste.
The early 1970's brought into the forefront a new heightened
environmental awareness. This has manifested itself in the form
of the Clean Air Act, RCRA, Medical Waste Tracking Act (MWTA),
California Health and Safety Code, California Administrative
Code, Best Available Control Technology (BACT) and a myriad of
other environmental laws and legislation.
The RCRA list of medical wastes that need to be tracked include
at least seven categories:
- Cultures and Stocks - cultures
from medical and pathological laboratories, live and
attenuated vaccines, dishes & devices
- Pathological Wastes - body
parts, tissues, body fluids and containers
- Used Sharps - syringes,
hypodermic needles, scalpel blades blood vials, test
tubes, tubing used in animal or human patient care,
research or treatment
- Animal Waste - carcasses, body
parts, bedding, fluids
- Human Blood and Blood Products
- serum, plasma blood components
- Isolation Waste - material
contaminated with blood, excretion
- Unused Sharps - scalpel blades,
syringes, hypodermic needles
PERCEIVED SOLUTIONS -
The preferred medical waste treatment method is on-site
where the waste generator can maintain full control of
processing. Onsite incineration is a popular choice when deciding
the method of disposal of hospital waste. Incineration reduces
weight and volume by 90 percent, assures complete destruction of
all pathogens and microorganisms and detoxifies chemical waste.
It also reduces the volume that must be landfilled. Additionally,
on-site incineration minimizes the risk associated when
contracting for transportation and processing by outside vendors.
Source of heat in an incinerator is the energy of the waste
itself, which is not enough energy for proper combustion. Natural
gas is added to enhance the combustion process. A proper
stoichiometric balance must exist in the incineration process for
complete combustion. To meet environmental regulations,
incinerators must reduce airborne pollutants and TACs. This
generally means the process must run in a "starved air"
condition, producing incomplete combustion. Incineration
emissions include by-products of benzene, dioxins, furans,
nitrogen oxides, sulfur dioxide, mercury and cadmium, all of
which must be removed from the gas stream. Most of the
by-products are considered TACs. Dioxins are formed as unwanted
by-products of incomplete combustion when chlorine and carbon
mixtures are present. Manufacturers use cadmium to make red bags
red. Cadmium is a heavy metal and TAC. In addition to the
emissions from incomplete combustion, considerable amounts of
energy are left in the bottom ash.
During recent years, regulatory agencies such as the EPA,
California Air Resources Board (CARB), South Coast Air Quality
Management District (SCAQMD) and the San Diego Air Pollution
Control District (SDAPCD) have taken an aggressive stand on
particulate and emissions discharges. The EPA indicates that 80
percent of the incinerators in the United States will cease to
operate due to more stringent regulations.
COMPOSITION OF
MEDICAL WASTE -
The composition of medical waste is similar to the
composition of municipal solid waste except that it is classified
as infectious and may contain more moisture. In order to quantify
the waste stream, Kaiser Permanente commissioned a study to
examine the waste stream at our Sunset Medical Center in
Hollywood, California. From the study, a Solid Waste Management
Plan was prepared by Waste Energy Technologies, Inc. Development
of the Plan was based on actual generation of waste rates.
Composition was determined through weighing and sorting of all
waste. According to the report, the facility generates 8,600
pounds of solid waste per day.
The attached charts developed by Waste Energy Technologies show
clear bag composition in "Figure l"; red
bag composition in "Figure 2"; and,
kitchen waste in "Figure 3".
Composition of the waste stream includes a significant
concentration of polyvinyl chloride plastic (PVC) and other
plastics. In the combustion process PVC breaks down and forms
hydrogen chloride (HCl) gas. If this waste stream were
incinerated, most plastics would form HCl that would result in
hydrochloric acid. This is a highly corrosive by-product.
According to the EPA, ash from the incineration process is
considered a hazardous material. Landfilling medical waste, ash
residue and other hazardous compounds carries with it a lifetime
ability. It is difficult to argue for incineration as an answer
to the waste disposal problem due to emission from the combustion
process. Emissions produced in the incineration process cannot be
economically scrubbed to a level that would eliminate TACs and
particulate discharge.
To render the hospital waste stream environmentally benign, any
process considered must eliminate all TACs, particulate discharge
and provide complete destruction of all pathogens and
microorganisms. It also must vitrify all ash residue preventing
the possibility of leaching into groundwater supplies.
PLASMA ENERGY -
Plasma energy technology was originally used more than 30
years ago in the space program to simulate the torrid
temperatures of reentry into the earth's atmosphere. Research
laboratories, steel mills, reactive metal industries and metal
cutting are among the fields in which plasma energy technology is
a proven application. Plasma systems assist in aluminum recovery,
heat vacuum furnaces for titanium processing and provide heat in
glass and ceramic processing.
Plasma energy is a naturally-occurring source and is the most
prevalent state of the universe. Lightning - the discharging of
static electricity that occurs in thunderstorms - is an example
of naturally-occurring plasma energy. Plasma is often called the
fourth state of matter. Plasma energy is actually heat energy
produced when electric current flows through a gas. Plasma forms
when electrical current ionizes a gas as electricity flows
through it, which is, heating by electricity. Resistance of the
ionized gas to the flow of electrical current (like any other
conductor) creates extremely high temperatures. This is the
essence of plasma energy. Gases such as helium argon, nitrogen or
air can be ionized to become the conductor. The plasma torch
converts electricity into heat energy by resistance heating using
a plasma column as the heating element.
TYPES OF PLASMA ARC
TORCHES -
Plasma arc torches are hardware used in a heating process and
can be adapted for many applications in industry. There are two
types of torches typically produced, transferred arc and
non-transferred arc. For purposes of discussion, this project
will incorporate the use of a transferred arc torch. The
transferred arc torch uses the working material to conduct
electricity. The photo shown above is a transferred arc torch.
Polarity is in the rear electrode and its negative polarity is
the working surface. This results in an intense, direct heat that
is ideal for pyrolysis of hospital waste.
The non-transferred arc torch uses two internal electrodes.
Injecting a small amount of ionized gas extends the plasma flame
beyond the tip of the torch. The non-transferred arc produces a
more dispersed heat for annealing and drying processes. (Both
torch types are shown in "Figure 4").
PLASMA PYROLYSIS;
THE REAL SOLUTION -
The intense heat of plasma energy has the effect of changing
solid materials chemically. This process is called pyrolysis.
Pyrolysis is the chemical change of material brought about by the
action of intense heat in the absence of oxygen. Instantaneous
arc temperatures of 21,000 degrees Fahrenheit converts all
organic material into basic atoms that recombine into simple
gases. The waste is not burned or combusted, but is pyrolyzed at
high temperatures. Combustion does not occur and ash does not
form in the pyrolysis process. The intense heat developed in
plasma causes molecules to separate randomly during pyrolysis.
The resulting fragments coalesce to form compounds and gases (See
"Figure 5"). The combination of high
temperature in the absence of air and a controlled input of steam
converts organic and solid materials into a vitreous substance
and a hydrogen-rich, clean gas. Plasma pyrolysis electrically
converts organic and inorganic material into a glassy residue and
clean fuel.
Pyrolysis is a clean and effective method for rendering hospital
and municipal solid waste environmentally benign. In essence, the
plasma pyrolysis process recycles waste in an environmentally
sound and safe manner. It protects and enhances our environment.
(See "Figure 5")
DEMONSTRATION
APPLICATION -
The health care industry is beginning to apply plasma energy
technology to dispose of medical waste in an efficient and safe
manner. A plasma demonstration project is permitted at the Kaiser
Permanente Medical Center, 4647 Zion Avenue, San Diego,
California. This 328 bed medical facility is the first in the
United States to obtain a permit to use plasma pyrolysis to treat
medical waste. (See "Figure 6")
In this history making project, hospital waste will be pyrolyzed
with a plasma arc torch. The 500KW plasma arc torch, engineered
by Mason & Hanger National, Inc., is designed to process
waste at 1000 pounds per hour. Because it is not a combustion
process, the volume of gases produced is one-sixth to one-tenth
the volume of gases produced by an incinerator. Plasma energy
captures the energy contained in the waste that would otherwise
be lost in landfills. The composition of the gas produced in the
pyrolysis process is listed below.
The plasma pyrolysis process has many advantages over
conventional incineration of hospital waste. Plasma-arc torches
produce the lowest-mass sustainable heating source available. The
temperatures achieved in the plasma process are the highest
controlled sustainable temperatures known. Fuel gas produced in
the process may be used as feedstock in boilers to make steam or
in other processes. Some of the advantages of plasma energy
include:
- Up to 200:1 solid volume reduction
- Solid weight reduction -- 2000
pounds to 100 pounds slag
- 100% recyclable by-products
- Eliminates landfill requirements
- Eliminates long term liability for
infectious waste
- Environmentally benign
- Precise temperature and process
control
- Maintain control from "cradle to
grave"
USE OF RYDROGEN-RICH
FUEL GAS -
The product gas may be used in many various energy intensive
applications including production of methanol. A cost benefit
analysis was performed to determine the highest and best use of
the product gas for our application. A 500KW plasma torch is not
large enough to economically produce product gas in sufficient
quantities as feedstock for methanol production. A central plant
that serves many hospitals would require a torch large enough to
make it cost effective for methanol production. Municipal
landfills would be prime candidates for plasma pyrolysis systems
requiring large torches.
The hydrogen-rich fuel gas produced by the plasma torch can be
used as feedstock for boilers, chillers or fuel cells. (See
"Figure 7")
The fuel cell shares many characteristics of a battery--no moving
parts, silent operation, and a electrochemical reaction to
generate energy. Chemical reaction in the cell is the combination
of hydrogen ions and oxygen ions interacting to form water,
producing electrical and thermal energy. The hydrogen-rich fuel
produced in the plasma torch is an ideal match for the fuel cell.
The combination of two emerging technologies used to recycle
hospital waste is recycling in its highest form. The medical
center's converted waste stream will produce two forms of energy
from the fuel cell. This electrical and thermal energy can be
used at the medical center.
USE OF GLASSY SLAG -
The plasma pyrolysis process is an environmentally clean
process. It generates heavy metals that are encapsulated within
the glassy slag. EP Toxicity tests of the glassy slag indicate
that the vitrification process encapsulates cadmium, lead,
mercury, chromium and TACs. The vitrified solid from the plasma
torch contains the balance of the waste products that did not
change into gas. These will not release heavy metals or pollution
to the environment. Permissible concentrations of the EP Toxicity
test are listed below. Each ton of medical waste processed will
produce 100 pounds of slag.
As mentioned earlier, the glassy slag can be used for concrete
aggregate, road bed construction, composition roofing and may
even be spun into insulation. In Japan the slag is used to build
decorative water fountains. Paper weights, pendants, trinkets and
glass tiles are other possible uses for the slag.
CONCLUSION
This exciting, historic project will revolutionize the way
society processes waste. Plasma pyrolysis of municipal solid
waste can yield 75 gallons of methanol for each ton of waste
processed. Essentially, a landfill could be mined (reformed) with
plasma pyrolysis for its rich source of carbon monoxide and
hydrogen. These are the basic building blocks in producing
methanol. Landfills can be an excellent source for a clean
transportation fuel.
High temperature thermal reduction, or pyrolysis, is the most
effective and environmentally benign process of waste reduction
to date. Controlled plasma temperatures of 21,000 degrees
Fahrenheit render all organics, pathological and biological waste
inert. The plasma pyrolysis process converts medical and
municipal solid waste into a clean hydrogen-rich gas and glassy
slag. Plasma produces no TACs, dioxins, cadmium or other harmful
emissions. Plasma heating can achieve temperatures not possible
by fossil fuel heaters. Pyrolysis results in a reduction of over
90 percent the volume of material. On-site plasma pyrolysis
process disposes of hospital waste, thus eliminating the need to
transport it on public streets and bury it in landfills. Lifetime
liabilities are virtually eliminated for the waste stream
generator and landfill operator.
HI Disposal Systems, LLC management has made the commitment to
promote energy conservation, reduce environmental pollution and
provide a healthier place to work and live for our neighbors and
employees. Using Plasma pyrolysis for the destruction of medical
waste is a demonstration of our progressive leadership in the
waste management industry. (See "Emissions Charts")
Note - page still
under construction - for "figures and exhibits", please
call: 800-995-1265
Hawkins Industries, Inc. & HI Disposal Systems, LLC = HI Companies
Mailing Address: P.O. Box 1724, Indianapolis, IN 46206-1724 USA
Voice: 317-693-1265 or 800-995-1265 - Fax: 317-262-1265 or 800-973-1265
(e-mail: info@hicompanies.com - web site: www.hicompanies.com)
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